Ionisation Energy (AQA A-Level Chemistry): Flashcards

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Ionisation Energy
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Definition of ionisation energy

Energy required to remove an electron from an atom or ion

First ionisation energy definition

Energy to remove 1 mol e⁻ from 1 mol gas atoms → 1 mol +1 ions

Units of ionisation energy

kJ/mol (kilojoules per mole)

First ionisation energy equation for element XX

X(g)X+(g)+eX(g) \rightarrow X^+(g) + e^-

Successive ionisation energies meaning

Energy needed to remove more than one electron from an atom

Why successive IEs increase (nuclear factor)

Electron removed is closer to the nucleus

Why successive IEs increase (shielding factor)

Fewer electrons to shield attraction from nucleus

Pattern of successive ionisation energies

Always higher than the previous one

Second ionisation energy equation for XX

X+(g)X2+(g)+eX^+(g) \rightarrow X^{2+}(g) + e^-

Third ionisation energy equation for XX

X2+(g)X3+(g)+eX^{2+}(g) \rightarrow X^{3+}(g) + e^-

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