Ionisation Energy: Trends & Evidence (AQA A-Level Chemistry): Flashcards

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Ionisation Energy: Trends & Evidence
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Effect of greater atomic radius on ionisation energy

Less energy required to ionise

Atomic radius trend across a period

Decreases

Effect of increased nuclear charge on ionisation energy

Higher ionisation energy

Effect of shielding by inner electrons

Reduces energy required to remove outer electrons

First ionisation energy trend down a group

Decreases

First ionisation energy trend across a period

Increases

Why Group 3 elements show drop in ionisation energy

Electron enters higher-energy p-orbital, more shielded

Why Group 6 elements show drop in ionisation energy

Electron pairing in p-orbital causes repulsion

Why Al has lower ionisation energy than Mg

Electron removed from 3p orbital, not 3s

Large jumps in successive ionisation energies indicate

Electron removed from lower energy level closer to nucleus

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