Transition Elements (OCR A-Level Chemistry A): Flashcards

📚Flashcards
Formation and Shapes of Complex Ions
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Complex ion definition

Molecules/ions bonded to central metal via coordinate bonds

Ligand definition

Molecule/ion donating electron pair to central metal ion

Coordinate bond key feature

Both electrons in bond come from same atom (the ligand)

Coordination number meaning

Number of coordinate bonds attached to central metal ion

Monodentate ligand

Ligand donating one electron pair to metal ion

Bidentate ligand

Ligand donating two electron pairs to metal ion

Octahedral: coordination no. & bond angle

Coordination number 6, bond angles 90°

Tetrahedral: coordination no. & bond angle

Coordination number 4, bond angles 109.5°

Square planar: coordination no. & bond angle

Coordination number 4, 90° angles, all ligands in same plane

Complex ion overall charge equals

Metal ion charge + sum of all ligand charges

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