Acid-Base Reactions of Organic Compounds (Leaving Cert Chemistry): Flashcards

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Acid-Base Reactions of Organic Compounds
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Functional group in alcohols

Hydroxyl group (-OH)

Acidity of alcohols vs water

Alcohols are weaker acids than water

Gas from Na + ethanol reaction

Hydrogen gas (H2H_2)

Salt from Na + ethanol

Sodium ethoxide (C2H5O−Na+C_2H_5O^-Na^+)

Functional group in carboxylic acids

Carboxyl group (-COOH)

Why is carboxylate ion stable?

Resonance - negative charge spread over 3 atoms

What is the inductive effect?

Electron-withdrawing groups stabilise carboxylate ion

Products: CH3COOHCH_3COOH + NaOHNaOH

Sodium ethanoate + water

Gas from carboxylic acid + carbonate

Carbon dioxide (CO2CO_2)

Test for carbon dioxide

Turns limewater milky

Gas from carboxylic acid + metal

Hydrogen gas (H2H_2)

Test for hydrogen gas

'Pop' sound with lighted taper

Acidity: alcohols vs carboxylic acids

Carboxylic acids are much stronger acids

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