The Lithium-Ion Cell (Leaving Cert Chemistry): Flashcards

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The Lithium-Ion Cell
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What is a lithium-ion cell?

Rechargeable battery using Li⁺ ion movement between electrodes

Why is lithium ideal for batteries?

Most reactive metal in Group 1; small size and light weight

Carbon electrode material

Graphite

What is intercalation?

Li⁺ ions sliding between carbon layers in graphite

Active material in cobalt oxide electrode

Cobalt dioxide (CoO2\text{CoO}_2)

Electrolyte function

Highway for Li⁺ ions; blocks electron passage

Separator function

Prevents short circuit; allows Li⁺ ions through

Type of cell during discharge

Galvanic cell (spontaneously produces electrical energy)

Type of cell during charging

Electrolytic cell (external energy reverses reaction)

Oxidation at carbon electrode (discharge)

LiC6→Li++e−+C6\text{LiC}_6 \rightarrow \text{Li}^+ + e^- + \text{C}_6

Reduction at cobalt oxide (discharge)

Li++e−+CoO2→LiCoO2\text{Li}^+ + e^- + \text{CoO}_2 \rightarrow \text{LiCoO}_2

Li⁺ ion flow direction during discharge

Carbon electrode → cobalt oxide electrode

Li⁺ ion flow direction during charging

Cobalt oxide electrode → carbon electrode

% of lithium-ion batteries currently recycled

5-10%

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