Accuracy and Precision in Volumetric Analysis (Leaving Cert Chemistry): Flashcards

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Accuracy and Precision in Volumetric Analysis
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What is accuracy?

How close a measurement is to the true value

What is precision?

How close repeated measurements are to each other

High accuracy & high precision pattern

Shots near centre & grouped together

Low accuracy & high precision pattern

Shots grouped together but away from centre

Why does accuracy matter in volumetric analysis?

Ensures correct concentration values

Why does precision matter in experiments?

Indicates reliability & consistency of technique

Equipment precaution for accuracy

Use properly calibrated equipment

How to prevent parallax errors

Take readings at eye level

How to rinse burettes & pipettes correctly

Rinse with the solution they will contain, not water

Endpoint control technique

Add solution drop-by-drop near endpoint

Common cause of accuracy errors

Incorrectly calibrated equipment

Common cause of precision errors

Inconsistent technique between measurements

23.5, 23.6, 23.7 cm3cm^3 vs true 23.0 cm3cm^3

Good precision, poor accuracy

Effect of not rinsing burette with solution

Water dilutes solution, affecting accuracy

Where are accuracy & precision crucial industrially?

Pharmaceutical manufacturing quality control

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