Volumetric Problems (Leaving Cert Chemistry): Flashcards

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Volumetric Problems
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What volumetric problems determine

Concentration of unknown solution using titration data

General volumetric formula

Va×Ma/na=Vb×Mb/nbV_a \times M_a / n_a = V_b \times M_b / n_b

Simplified formula for 1:1 acid-base reactions

Va×Ma=Vb×MbV_a \times M_a = V_b \times M_b

What VaV_a represents in volumetric formula

Volume of acid (cm³)

What MaM_a represents in volumetric formula

Molarity of acid (mol/L)

What nan_a represents in volumetric formula

Number of moles of acid from balanced equation

Why use average titration values

Reduces experimental error and gives more accurate results

First step in volumetric analysis

Identify unknown, write balanced equation, list given data

Mole ratio in Na₂CO₃ + 2HCl reaction

1:2 ratio (one Na₂CO₃ to two HCl)

Mole ratio in HCl + NaOH reaction

1:1 ratio

How to handle dilution factors

Multiply calculated concentration by dilution factor

Typical units for final concentration

mol/L or g/L

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