Volumetric Analysis: Oxidation-Reduction (LC 2027) (Leaving Cert Chemistry): Flashcards

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Random and Systematic Errors
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Experimental error definition

Difference between measured and true value

Two main categories of experimental error

Systematic error and random error

Systematic error definition

Consistent repeating error in same direction

Direction of systematic error measurements

Always higher OR always lower than true value

Does systematic error affect accuracy or precision?

Accuracy

Can systematic errors be completely eliminated?

Yes

Parallax error

Systematic error from reading meniscus at wrong angle

Random error definition

Unpredictable fluctuation in measurements

Direction of random error measurements

Unpredictable - can be higher or lower than true value

Does random error affect accuracy or precision?

Precision

Can random errors be completely eliminated?

No, only minimised

Key method to minimise systematic errors

Proper calibration and correct procedures

Key method to minimise random errors

Take multiple measurements and calculate average

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