Unsaturated Hydrocarbon Reactions (HSC SSCE Chemistry): Flashcards

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Unsaturated Hydrocarbon Reactions
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Unsaturated hydrocarbons

Alkenes (C=C double bonds) and alkynes (C≡C triple bonds)

Why unsaturated hydrocarbons more reactive

Double/triple bonds weaker & easier to break than single bonds

Complete combustion products

CO2\text{CO}_2 and H2O\text{H}_2\text{O} only

Addition reaction

Atoms added by breaking multiple bond; all atoms in product

Hydrogenation

Adding H2\text{H}_2 to unsaturated hydrocarbon

Hydrogenation catalysts

Metal catalysts: Ni, Pt, Pd, or Rh

Halogenation catalyst needed?

No - halogens highly reactive

Bromine water test result

Unsaturated compounds decolourise bromine water

Alkene hydration product

Alcohols

Markovnikov's rule

H adds to carbon with more H atoms already attached

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