Percentage Composition, Empirical and Molecular Formulas (VCE SSCE Chemistry): Flashcards

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Percentage Composition, Empirical and Molecular Formulas
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Percentage composition by mass definition

Proportion of compound's mass from each element as a percentage

Formula for % composition of an element

element mass in 1 molmolar mass×100\frac{\text{element mass in 1 mol}}{\text{molar mass}} \times 100

Empirical formula definition

Simplest whole-number ratio of atoms of each element in a compound

Molecular formula definition

Actual number of atoms of each element present in a molecule

Why ionic compounds use only empirical formulas

They form crystal lattices, not discrete molecules

Formula to calculate moles from mass

n=mMn = \frac{m}{M} where nn=moles, mm=mass, MM=molar mass

Key fact in combustion analysis for hydrogen

Each water molecule contains 2 hydrogen atoms - multiply by 2

Formula for number of empirical units in molecular formula

molar mass of compoundempirical formula mass\frac{\text{molar mass of compound}}{\text{empirical formula mass}}

Relationship between molecular and empirical formulas

Molecular formula is a whole-number multiple of empirical formula

First step with percentage composition data

Assume 100 g of compound; percentages become masses in grams

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