Shapes of Simple Molecules & Ions (AQA A-Level Chemistry): Flashcards

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Shapes of Simple Molecules & Ions
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Electron pairs described as

Charge clouds that repel each other

Strongest electron pair repulsion type

Lone pair-lone pair

Effect of more lone pairs on bond angle

Bond angle decreases

Bond angle in linear shape (e.g., CO2CO_2)

180°180°

Bond angle in trigonal planar (e.g., BF3BF_3)

120°120°

Bond angle in tetrahedral (e.g., CH4CH_4)

109.5°109.5°

Shape & angle of NH3NH_3

Trigonal pyramidal, 107°107°

Shape & angle of H2OH_2O

Bent/V-shaped, 104.5°104.5°

Bond angle in octahedral (e.g., SF6SF_6)

90°90°

Why lone pairs cause greater repulsion

Attracted to only one nucleus, take up more space

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