Hess' Law (AQA A-Level Chemistry): Flashcards

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Hess' Law
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Hess' Law definition

Total enthalpy change same regardless of route taken

Principle behind Hess' Law

Energy conservation

Conditions for Hess' Law to apply

Initial and final conditions must be the same

Purpose of Hess' Law

Calculates ΔH\Delta H that can't be measured directly

Hess Cycle

Cycle connecting different reaction routes

Triangular enthalpy cycle

Common method for applying Hess' Law

Arrows in Hess Cycle

Represent enthalpy changes for reaction stages

Forward arrow in Hess Cycle

Values are added

Reverse arrow in Hess Cycle

Values are subtracted

How are arrows treated in Hess Cycle?

As vectors (directional)

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