Time of Flight Mass Spectrometry (AQA A-Level Chemistry): Quizzes

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Time of Flight Mass Spectrometry
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What data does TOF mass spectrometry provide?

Relative isotopic masses & abundance

In electrospray ionisation, how do particles become positive ions?

They gain a proton H+H^+

What type of ions does electron impact ionisation produce?

+1+1 ions

In the acceleration stage, all ions receive the same what?

Kinetic energy

Which ions reach the detector first in the ion drift stage?

Lighter ions

What produces the current at the detector?

Ions gaining an electron

What does the base peak represent in a mass spectrum?

The most abundant ion

Which magnesium isotope appears as the base peak with the highest abundance?

24Mg+^{24}\text{Mg}^+ at m/z = 24

In Cl2Cl_2 mass spectrum, what does the peak at m/z = 72 represent?

35Cl−37Cl+^{35}\text{Cl}-^{37}\text{Cl}^+

What causes the small peak at m/z = 47 in ethanol's mass spectrum?

Presence of 13C^{13}C atom

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