Time of Flight Mass Spectrometry (AQA A-Level Chemistry): Flashcards

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Time of Flight Mass Spectrometry
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Use of TOF mass spectrometry

Identify elements, determine relative molecular masses & isotopic abundance

Electrospray ionisation process

Sample in solvent, high voltage needle, particles gain H+H^+

Electron impact ionisation product

High-energy electrons knock off electrons, forming +1 ions

Ion velocity after acceleration

Same kinetic energy given, but lighter ions move faster than heavier ions

Which ions arrive at detector first

Lighter ions

What produces current in detector

Ions gaining electrons produces current

Mass spectrum axes

x-axis: m/zm/z values, y-axis: relative abundance

Base peak definition

Tallest peak, most abundant ion

Molecular ion peak

Peak corresponding to molecular mass of compound

Cause of small peak at m/z=47m/z = 47 in ethanol

Presence of 13C^{13}C atom

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