Time of Flight Mass Spectrometry (AQA A-Level Chemistry): Flashcards
📚Flashcards
Practise the cards
10 cards from this deck
ShowHide
Practise the cards
10 cards from this deck
Use of TOF mass spectrometry
Use of TOF mass spectrometry
Identify elements, determine relative molecular masses & isotopic abundance
Electrospray ionisation process
Electrospray ionisation process
Sample in solvent, high voltage needle, particles gain
Electron impact ionisation product
Electron impact ionisation product
High-energy electrons knock off electrons, forming +1 ions
Ion velocity after acceleration
Ion velocity after acceleration
Same kinetic energy given, but lighter ions move faster than heavier ions
Which ions arrive at detector first
Which ions arrive at detector first
Lighter ions
What produces current in detector
What produces current in detector
Ions gaining electrons produces current
Mass spectrum axes
Mass spectrum axes
x-axis: values, y-axis: relative abundance
Base peak definition
Base peak definition
Tallest peak, most abundant ion
Molecular ion peak
Molecular ion peak
Peak corresponding to molecular mass of compound
Cause of small peak at in ethanol
Cause of small peak at in ethanol
Presence of atom
