Ionisation Energies (OCR A-Level Chemistry A): Flashcards
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First ionisation energy definition
First ionisation energy definition
Energy to remove 1e⁻ from each atom in 1 mol gas atoms to 1+ ions
General equation for first ionisation
General equation for first ionisation
Three factors affecting ionisation energy
Three factors affecting ionisation energy
Atomic radius, nuclear charge, electron shielding
Why successive ionisation energies increase
Why successive ionisation energies increase
Less e⁻ repulsion & stronger nuclear attraction on remaining e⁻
Large jumps in successive IE meaning
Large jumps in successive IE meaning
Electron removed from inner shell closer to nucleus
First IE trend down a group
First IE trend down a group
Decreases
Why first IE decreases down a group
Why first IE decreases down a group
Radius & shielding increase outweigh nuclear charge increase
First IE trend across a period
First IE trend across a period
Generally increases
Why first IE drops from Be to B
Why first IE drops from Be to B
2p electron higher energy than 2s, easier to remove
Why first IE drops from N to O
Why first IE drops from N to O
Paired e⁻ in O repel, easier to remove despite higher charge
