Ionisation Energies (OCR A-Level Chemistry A): Flashcards

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Ionisation energies
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First ionisation energy definition

Energy to remove 1e⁻ from each atom in 1 mol gas atoms to 1+ ions

General equation for first ionisation

X(g)X+(g)+e\text{X(g)} \rightarrow \text{X}^{+}\text{(g)} + \text{e}^{-}

Three factors affecting ionisation energy

Atomic radius, nuclear charge, electron shielding

Why successive ionisation energies increase

Less e⁻ repulsion & stronger nuclear attraction on remaining e⁻

Large jumps in successive IE meaning

Electron removed from inner shell closer to nucleus

First IE trend down a group

Decreases

Why first IE decreases down a group

Radius & shielding increase outweigh nuclear charge increase

First IE trend across a period

Generally increases

Why first IE drops from Be to B

2p electron higher energy than 2s, easier to remove

Why first IE drops from N to O

Paired e⁻ in O repel, easier to remove despite higher charge

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