The Halogens (OCR A-Level Chemistry A): Flashcards

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The Halogens
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Periodic table group of halogens

Group 17 (also known as Group 7)

Physical state of Br2\text{Br}_2 at RTP

Red-brown liquid

Why halogen boiling points increase down group

More electrons cause stronger London dispersion forces

Number of outer electrons in halogen atoms

Seven electrons (ns2np5ns^2np^5)

Role of halogens in redox reactions

Oxidising agents (gain electrons, reduced to X−\text{X}^-)

Halogen reactivity trend down group

Decreases (weaker oxidising agents)

Why halogen reactivity decreases down group

Larger atomic radius & more shielding reduce nuclear attraction

Disproportionation definition

Same element simultaneously oxidised and reduced

Cl2\text{Cl}_2 + cold dilute NaOH product

Sodium chlorate(I), NaClO (household bleach)

Halide reducing power trend down group

Increases (I−>Br−>Cl−\text{I}^- > \text{Br}^- > \text{Cl}^-)

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