The Acid Dissociation Constant Ka (OCR A-Level Chemistry A): Flashcards

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The Acid Dissociation Constant Ka
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Strong acid behaviour in water

Complete dissociation

Weak acid behaviour in water

Partial dissociation, establishes equilibrium

General KaK_a expression

Ka=[H+][A][HA]K_a = \frac{[\text{H}^+][\text{A}^-]}{[\text{HA}]}

Units of KaK_a

mol dm3^{-3}

Large KaK_a value means

Stronger acid, more dissociation

pKa\text{pK}_a definition

pKa=logKa\text{pK}_a = -\log K_a

KaK_a from pKa\text{pK}_a formula

Ka=10pKaK_a = 10^{-\text{pK}_a}

Small pKa\text{pK}_a value means

Stronger acid (inverse to KaK_a)

Polybasic acid dissociation

Sequential steps, each with own KaK_a

Why 2nd dissociation weaker in dibasic acids

Removing H+^+ from negative ion needs more energy

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