Rate Constants and Temperature (OCR A-Level Chemistry A): Flashcards

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Rate constants and temperature
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Effect of temp increase on rate constant kk

kk increases exponentially

Rule: 10°C temp rise effect on rate constant

Approx. doubles kk and reaction rate

Type of relationship: rate constant vs temperature

Exponential, not linear

Primary factor: why temp increases kk

Boltzmann distribution shifts; more particles exceed EaE_a

Arrhenius equation (exponential form)

k=A⋅e−Ea/RTk = A \cdot e^{-E_a/RT}

Gas constant RR value and units

8.3148.314 J mol⁻¹ K⁻¹

Required units for TT in Arrhenius equation

Kelvin (K)

Logarithmic form of Arrhenius equation

ln⁡k=−EaR×1T+ln⁡A\ln k = -\frac{E_a}{R} \times \frac{1}{T} + \ln A

Gradient of ln⁡k\ln k vs 1T\frac{1}{T} graph

−EaR-\frac{E_a}{R} (negative)

Formula: calculate EaE_a from gradient

Ea=−gradient×RE_a = -\text{gradient} \times R

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