Electrode Potentials (OCR A-Level Chemistry A): Flashcards

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Electrode potentials
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Electrochemical cell

Device converting chemical energy to electrical energy

Half-cell

Contains all species in one half of a redox equation

Symbol for standard electrode potential

E°E°

Standard conditions for electrode potentials

298 K, 100 kPa, 1 mol dm−3^{-3}

Standard electrode potential of SHE

0 V

Salt bridge function in electrochemical cell

Allows ion flow between solutions, completes circuit

More positive E°E° value indicates

Greater tendency to gain electrons (undergo reduction)

More negative E°E° value indicates

Greater tendency to lose electrons (undergo oxidation)

Formula for standard cell potential

E°cell=E°(positive)−E°(negative)E°_{cell} = E°(positive) - E°(negative)

Electrode with more positive E°E° value

Positive electrode (cathode)

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