Calculating pH (Leaving Cert Chemistry): Flashcards

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Calculating pH
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pH stands for

Power of hydrogen

pH formula

pH=−log⁡10[H+]\text{pH} = -\log_{10}[\text{H}^+]

pOH formula

pOH=−log⁡10[OH−]\text{pOH} = -\log_{10}[\text{OH}^-]

Relationship between pH and pOH at 25°C

pH+pOH=14\text{pH} + \text{pOH} = 14

Strong acids in water

Completely dissociate (break apart)

[H+][\text{H}^+] for strong acids equals

Molarity × number of H+\text{H}^+ ions released

H2SO4\text{H}_2\text{SO}_4 releases how many H+\text{H}^+ ions

2 H+\text{H}^+ ions per molecule

Method to find pH of strong bases

Calculate pOH first, then use pH=14−pOH\text{pH} = 14 - \text{pOH}

When strong acid conc. decreases by factor of 10, pH

Increases by 1 unit

Weak acids in water

Only partially dissociate

KaK_a (dissociation constant) tells us

How much the acid dissociates

Simplified formula for [H+][\text{H}^+] in weak acids

[H+]=Ka×Macid[\text{H}^+] = \sqrt{K_a \times M_{\text{acid}}}

Weak vs strong acid pH at same concentration

Weak acids have higher pH values

Conductivity: strong vs weak acids

Strong acids: high; weak acids: lower

Traditional pH scale range at 25°C

0 to 14

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