Standard Solutions (Leaving Cert Chemistry): Flashcards

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Standard Solutions
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Definition of standard solution

Solution with precisely known concentration

Main use of standard solutions

Volumetric analysis and acid-base titrations

Definition of primary standard

Stable, pure, soluble solid that can be weighed accurately for standard solutions

First criterion for primary standards

High purity

Why high molecular mass needed in primary standards?

Minimises impact of weighing errors on precision

Why stability in air needed in primary standards?

Shouldn't lose/gain water from air

Why sulphuric acid not a primary standard?

It's hygroscopic (absorbs water vapour from air)

Why sodium hydroxide not a primary standard?

It's deliquescent (absorbs water to form solution)

Why hydrated sodium carbonate not primary standard?

It's efflorescent (loses water of crystallisation)

Three examples of primary standards

Anhydrous sodium carbonate, NaCl, potassium hydrogen phthalate

Define hygroscopic

Absorbs water vapour from air

Define deliquescent

Absorbs water from air to form a solution

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