Potassium Permanganate and Redox Titration 1 (Leaving Cert Chemistry): Flashcards

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Potassium Permanganate and Redox Titration 1
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Chemical formula of potassium permanganate

KMnO4\text{KMnO}_4

Colour of potassium permanganate solid

Purple

Role of KMnO4\text{KMnO}_4 in redox reactions

Strong oxidising agent

Special property of KMnO4\text{KMnO}_4 in titrations

Self-indicating

Why KMnO4\text{KMnO}_4 not a primary standard

Cannot obtain high purity, unstable, decomposes, conc. varies

Colour change: MnO4−\text{MnO}_4^- to Mn2+\text{Mn}^{2+} in acid

Purple to colourless

Ratio of MnO4−\text{MnO}_4^- to Fe2+\text{Fe}^{2+} in reaction

1:5

Endpoint colour in permanganate titration

Faint pink colour persists

Problem with FeSO4⋅7H2O\text{FeSO}_4 \cdot 7\text{H}_2\text{O}

Loses water of crystallisation (efflorescence)

Primary standard used instead of iron(II) sulfate

Ammonium iron(II) sulfate

Formula: ammonium iron(II) sulfate

(NH4)2SO4⋅FeSO4⋅6H2O(\text{NH}_4)_2\text{SO}_4·\text{FeSO}_4·6\text{H}_2\text{O}

Why acidic conditions needed in permanganate titration

Provides H+\text{H}^+ ions needed for reaction

Typical KMnO4\text{KMnO}_4 concentration for titrations

0.02 M

Where to read meniscus for purple KMnO4\text{KMnO}_4 solution

From the top (not bottom)

Definition: Efflorescence

Spontaneous loss of water of crystallisation

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