Redox Titration 2: Iodine and Sodium Thiosulfate (Leaving Cert Chemistry): Quizzes

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Redox Titration 2: Iodine and Sodium Thiosulfate
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What does the 'pent' in pentahydrate refer to in Na2S2O3⋅5H2O\text{Na}_2\text{S}_2\text{O}_3 \cdot 5\text{H}_2\text{O}?

Five water molecules in the structure

What does the prefix 'thio' indicate in thiosulfate ion structure?

Sulfur has replaced oxygen

What is the product when thiosulfate ions are oxidized by iodine?

Tetrathionate ion (S4O62−\text{S}_4\text{O}_6^{2-})

What is the molar ratio of iodine to thiosulfate in the titration reaction?

1:2

Why can't sodium thiosulfate be used to prepare standard solutions by direct weighing?

The crystals are efflorescent

When should starch indicator be added during the iodine-thiosulfate titration?

When the solution becomes pale yellow

In the iodine-thiosulfate reaction, which substance acts as the reducing agent?

Thiosulfate ion

What color change indicates the endpoint when starch indicator is used?

Blue-black suddenly disappears

Why is excess potassium iodide added to keep iodine in solution?

It forms triiodide ion (I3−\text{I}_3^-)

Why should iodine solutions be kept in dark bottles during storage?

To prevent decomposition

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