Redox Titration 2: Iodine and Sodium Thiosulfate (Leaving Cert Chemistry): Flashcards

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Redox Titration 2: Iodine and Sodium Thiosulfate
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Role of sodium thiosulfate in I2\text{I}_2 titration

Reducing agent

Formula of sodium thiosulfate pentahydrate

Na2S2O3⋅5H2O\text{Na}_2\text{S}_2\text{O}_3 \cdot 5\text{H}_2\text{O}

'Pent' meaning in pentahydrate

Five water molecules

Formula of thiosulfate ion

S2O32−\text{S}_2\text{O}_3^{2-}

Formula of tetrathionate ion

S4O62−\text{S}_4\text{O}_6^{2-}

Role of iodine in thiosulfate titration

Oxidising agent

Molar ratio I2:S2O32−\text{I}_2:\text{S}_2\text{O}_3^{2-} in reaction

1:2

Why Na2S2O3\text{Na}_2\text{S}_2\text{O}_3 not a primary standard?

Efflorescent - loses water, making accurate weighing impossible

When to add starch in I2\text{I}_2/thiosulfate titration?

When solution becomes pale yellow

Colour of starch-iodine complex

Blue-black

Endpoint indication in I2\text{I}_2/thiosulfate titration

Blue-black colour disappears

Meaning of prefix 'thio'

Sulfur has replaced oxygen

Triiodide ion formation equation

I2+I−→I3−\text{I}_2 + \text{I}^- \rightarrow \text{I}_3^-

Why store iodine solutions in dark bottles?

To prevent decomposition

Product when thiosulfate oxidised

Tetrathionate ion (S4O62−\text{S}_4\text{O}_6^{2-})

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