Calculations Involving Equilibrium (VCE SSCE Chemistry): Flashcards

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Calculations Involving Equilibrium
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Equilibrium constant (K) indicates

Extent of reaction at equilibrium

Effect on K when equation reversed

K becomes reciprocal: Kreverse=1KforwardK_{reverse} = \frac{1}{K_{forward}}

Effect on K when coefficients doubled

K is squared: Kdoubled=(Koriginal)2K_{doubled} = (K_{original})^2

Effect on K when coefficients halved

K is square root: Khalved=KoriginalK_{halved} = \sqrt{K_{original}}

Large K value (K > 10410^4) meaning

Reaction almost complete; products dominate

Small K value (K < 10410^{-4}) meaning

Very little reaction; reactants dominate

Intermediate K range and meaning

10410^{-4} < K < 10410^4; both reactants & products present

ICE table stands for

Initial, Change, and Equilibrium

Concentrations used to calculate K

Equilibrium concentrations (not initial)

CO vs O2O_2 K for haemoglobin binding

CO has K ~20,000 times larger than O2O_2

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