Stereoisomerism (AQA A-Level Chemistry): Quizzes

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Stereoisomerism
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What is stereoisomerism?

Same formula, different spatial arrangement

What causes restricted rotation around a C=CC=C double bond?

The pi bond

What must each carbon of a double bond have for E/Z isomerism to occur?

Two different groups attached

In a Z isomer, where are the highest priority groups?

On the same side of the double bond

In an E isomer, where are the highest priority groups?

On opposite sides of the double bond

In CIP priority rules, what determines which group has higher priority?

Higher atomic number

When directly attached atoms are identical, what determines priority?

Atoms further down the chain

Between BrBr and ClCl attached to a double bond carbon, which has higher priority?

BrBr

Between an ethyl group and a methyl group, which has higher priority?

Ethyl group

What effect does E/Z isomerism have on compounds?

Affects physical & chemical properties

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