Buffer Solutions (OCR A-Level Chemistry A): Flashcards

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Buffer solutions
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What buffer solutions resist

Changes in pH when small amounts of acid/base added

Two components of a buffer solution

Weak acid (HA) and its conjugate base (A⁻)

Role of weak acid in buffer

Removes added alkali

Role of conjugate base in buffer

Removes added acid

When buffer is most effective

When equal concentrations of HA and A⁻ are present

pH of buffer when [HA]=[A][\text{HA}] = [\text{A}^-]

pH=pKa\text{pH} = \text{pK}_a

Formula for [H+][\text{H}^+] in buffer

[H+]=Ka×[HA][A][\text{H}^+] = K_a \times \frac{[\text{HA}]}{[\text{A}^-]}

Typical buffer operating pH range

About 2 pH units either side of pKa\text{pK}_a

Two methods to prepare buffer

Weak acid + salt OR partial neutralization with alkali

When acid added to buffer, what happens

A\text{A}^- reacts with H+\text{H}^+, equilibrium shifts left

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