Enthalpy Changes in Solution (OCR A-Level Chemistry A): Flashcards

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Enthalpy Changes in Solution
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Def: ΔsolH∘\Delta_{\text{sol}}H^\circ

Enthalpy change when 1 mol solute dissolves completely

Def: ΔhydH∘\Delta_{\text{hyd}}H^\circ

Enthalpy change: gaseous ions to 1 mol aqueous ions

Two stages of ionic compound dissolving

Lattice breaks to gaseous ions; ions hydrate

Breaking ionic lattice: endo or exothermic?

Endothermic (energy needed to overcome attractions)

Hydration of ions: endo or exothermic?

Exothermic (always releases energy)

Hess's law for dissolution (components)

Lattice + solution enthalpy = sum of hydration enthalpies

Formula for energy change in solution

q=mcΔTq = mc\Delta T

mm in q=mcΔTq = mc\Delta T represents

Mass of solution (water + dissolved compound)

Temp decreases: ΔsolH\Delta_{\text{sol}}H sign?

Positive (endothermic)

Cold pack mechanism

Endothermic dissolution absorbs heat from surroundings

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