Stereoisomerism in Complex Ions (OCR A-Level Chemistry A): Flashcards

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Stereoisomerism in Complex Ions
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Stereoisomers definition

Same atoms/bonds, different 3D arrangement

Bond angle between identical ligands in cis isomer

90°90°

Bond angle between identical ligands in trans isomer

180°180°

Coordination number in square planar complex

4

Coordination number in octahedral complex

6

Bidentate ligand

Forms 2 coordinate bonds to metal ion

Optical isomerism requirement in complex ions

Octahedral with 2+ bidentate ligands

Trans isomers and optical isomerism

Cannot show optical isomerism

Cisplatin formula

[Pt(NH3)2Cl2][\text{Pt}(\text{NH}_3)_2\text{Cl}_2]

Cisplatin mechanism

Binds DNA, prevents replication, causes cell death

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