Stereoisomerism in Complex Ions (OCR A-Level Chemistry A): Quizzes

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Stereoisomerism in Complex Ions
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What defines stereoisomers in complex ions?

Same atoms, same bonds, different 3D space

What is the bond angle between identical ligands in a cis isomer of a square planar complex?

90°90°

What is required for cis-trans isomerism in square planar complexes?

Coordination number 4, two pairs identical

For octahedral cis-trans with monodentate ligands, what ratio of ligands is needed?

Four of one type, two of another

What colors are the cis and trans isomers of [Co(NH3)4Cl2]+[\text{Co}(\text{NH}_3)_4\text{Cl}_2]^+?

Cis is violet, trans is green

What defines a bidentate ligand?

Forms two coordinate bonds to metal

What is required for optical isomerism in complex ions?

Octahedral with 2+ bidentate ligands

Why can't trans isomers show optical isomerism?

Mirror image is superimposable

How does cisplatin prevent cancer cell division?

Binds to DNA, prevents replication

Why is the cis form of [Pt(NH3)2Cl2][\text{Pt}(\text{NH}_3)_2\text{Cl}_2] medically active but trans isn't?

Cis forms correct DNA cross-links

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