Spectroscopy (OCR A-Level Chemistry A): Quizzes

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Mass Spectrometry
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What is the primary purpose of mass spectrometry in organic chemistry?

To identify compounds by molecular mass

What is a molecular ion (M+\text{M}^+) in mass spectrometry?

A molecule that loses one electron

Where does the M⁺ peak appear on a mass spectrum?

At the highest m/zm/z value

What causes the M+1 peak in a mass spectrum?

Presence of carbon-13 isotope

What percentage of naturally occurring carbon atoms are carbon-13?

1.1%

M peak height is 74 mm, M+1 peak is 4.5 mm. How many carbon atoms are present?

6

In fragmentation, what species are detected by the mass spectrometer?

Only positively charged fragment ions

Why do isomers produce different mass spectra despite having the same molecular mass?

They have different fragmentation patterns

What is the m/zm/z value for the fragment ion C2H5+\text{C}_2\text{H}_5^+?

29

By how many mass units do successive alkyl cation fragments increase?

14 (one CH2\text{CH}_2 group)

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