Alkanes (OCR A-Level Chemistry A): Flashcards

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Properties of Alkanes
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General formula of alkanes

CnH2n+2\text{C}_n\text{H}_{2n+2}

Type of hydrocarbon that alkanes are

Saturated hydrocarbons

Name for single covalent bonds in alkanes

Sigma bonds (σ\sigma-bonds)

How sigma bonds form

Direct overlap of two atomic orbitals

Bond angle in tetrahedral geometry

Approximately 109.5°109.5°

Number of sigma bonds each C atom forms in alkanes

Four

Effect of chain length on alkane boiling point

Increases with longer chains

Why longer alkanes have higher boiling points

Larger surface area, stronger London forces

Boiling point of branched vs straight-chain isomers

Branched have lower boiling points

Why branched alkanes have lower boiling points

Compact shape, less surface contact, weaker London forces

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