Basic Concepts of Organic Chemistry (OCR A-Level Chemistry A): Flashcards

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Introduction to reaction mechanisms
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What reaction mechanisms reveal

Step-by-step process of how reactions actually happen

Homolytic fission

Bond breaks evenly; each atom gets one electron from the pair

Species with unpaired electrons

Radicals

Heterolytic fission

Bond breaks unevenly; one atom takes both electrons

Products of heterolytic fission

Negative ion (anion) and positive ion (cation/carbocation)

What full curly arrows show in mechanisms

Movement of an electron pair

What fish-hook arrows represent

Movement of a single electron

Addition reaction

Two molecules combine to form a single product

Substitution reaction

One atom or group replaced by a different atom or group

Elimination reaction

Small molecule removed, forming a double bond

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