Electrolysis to extract metals (Edexcel GCSE Chemistry Combined Science): Flashcards

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4.3.3 Using Electrolysis to Extract Metals
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Method to extract reactive metals from ores

Electrolysis

Primary ore of aluminium

Bauxite

Chemical formula of bauxite (aluminium oxide)

Al2O3Al_2O_3

Why is cryolite mixed with bauxite?

To lower the melting point

Type of electrodes in aluminium extraction

Graphite electrodes

Ions attracted to cathode in aluminium extraction

Aluminium ions (Al3+Al^{3+})

What happens to Al3+Al^{3+} ions at cathode?

Gain electrons (reduction)

Half-equation at cathode for aluminium

Al3++3eAl(l)Al^{3+} + 3e^- \to Al(l)

What happens to molten aluminium in cell?

Sinks to bottom (denser than mixture)

Ions attracted to anode in aluminium extraction

Oxide ions (O2O^{2-})

What happens to O2O^{2-} ions at anode?

Lose electrons (oxidation)

Half-equation at anode for oxygen

2O2O2(g)+4e2O^{2-} \to O_2(g) + 4e^-

Gas produced when oxide ions react with carbon anode

Carbon dioxide (CO2CO_2)

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