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10 cards from this deck
Alkanes with H atoms replaced by halogen atoms (F, Cl, Br, I)
CnH2n+1X\mathrm{C_nH_{2n+1}X}CnH2n+1X where X is a halogen
Fluoro-, chloro-, bromo-, iodo-
Halogen more electronegative than C, creates δ+\delta^+δ+ and δ−\delta^-δ−
Larger halogen = higher bp (I > Br > Cl > F)
Decreases - non-polar hydrocarbon part becomes dominant
Polar C-X bond makes C susceptible to nucleophile attack
Alcohol (halogen replaced by -OH group)
UV breaks C-Cl bond, releasing Cl radicals that destroy O₃
Cl acts as catalyst - regenerated after each reaction cycle
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