Trends in Physical Properties Within Homologous Series (VCE SSCE Chemistry): Quizzes

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Trends in Physical Properties Within Homologous Series
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Why do alkanes show increasing boiling points as carbon chain length increases?

Stronger dispersion forces & more contact

Why does butane have a higher boiling point (0.5°C-0.5°C) than methylpropane (11.7°C-11.7°C)?

Butane is linear; fits closer together

Why do haloalkanes have higher boiling points than alkanes with similar carbon atoms?

Dipole-dipole forces plus dispersion

What happens to viscosity as hydrocarbon chain length increases?

Viscosity increases

Which compound can form hydrogen bonds with itself?

Propan-1-ol

Rank these butanol isomers by boiling point (highest to lowest):

Butan-1-ol > Butan-2-ol > 2-methylpropan-2-ol

Why do carboxylic acids have particularly high boiling points?

Form dimers held by two hydrogen bonds

Why can't aldehydes and ketones form hydrogen bonds with each other?

No H atom bonded directly to O or N

Rank intermolecular forces by strength (strongest to weakest):

Hydrogen bonding > Dipole-dipole > Dispersion

What effect does increasing temperature have on the viscosity of liquids?

Viscosity decreases

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