Nuclear Magnetic Resonance Spectroscopy (A Level only) (AQA A-Level Chemistry): Flashcards

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Principles of NMR
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Purpose of NMR spectroscopy

Determines molecular structure of compounds

Isotopes used in NMR

13C^{13}C and 1H^1H

Why 13C^{13}C and 1H^1H are used in NMR

They have nuclear spin

Low-energy spin state name in NMR

α-spin state (aligned with field)

High-energy spin state name in NMR

β-spin state (opposed to field)

Definition of resonance in NMR

Energy absorption causing spin flip from α to β state

Energy needed by shielded nuclei

Less energy (electron cloud reduces magnetic field effect)

Energy needed by deshielded nuclei

More energy (stronger effective magnetic field)

Unit of chemical shift measurement

ppm (parts per million)

Standard reference substance in NMR

TMS (tetramethylsilane)

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