Quaternary Ammonium Salts (AQA A-Level Chemistry): Flashcards

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Quaternary Ammonium Salts
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Quaternary ammonium salts

All 4 H in NH4+NH_4^+ replaced by alkyl groups

Structural feature of quaternary ammonium salts

Positively charged N with no H atoms directly attached

Example quaternary ammonium salt

Tetraethylammonium bromide

Efficiency of quaternary salt formation

Low - multiple substitutions give mixture of products

Why no further N reactions in quaternary salts

All 4 H atoms already replaced by alkyl groups

N charge in quaternary ammonium salts

Full positive charge (N+N^+)

Industrial uses of quaternary ammonium salts

Hair conditioners, fabric softeners

Surfactant type of quaternary ammonium salts

Cationic surfactants

Hydrophilic part of quaternary ammonium salts

Positively charged N+N^+ end

Mechanism in conditioners (quaternary salts)

++ charge attracts to - surfaces, forms coating

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