Aromatic Chemistry (OCR A-Level Chemistry A): Quizzes

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Electrophilic substitution of benzene
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What is the characteristic reaction type for benzene?

Electrophilic substitution

What temperature is used for nitration of benzene, and what happens if it is exceeded?

50°C; further substitution occurs

What is the electrophile in the nitration of benzene?

NO2+NO_2^+ nitronium ion

What is the role of concentrated H2SO4H_2SO_4 in the nitration of benzene?

Catalyst

Which catalyst is required for the bromination of benzene?

FeBr3FeBr_3 or AlBr3AlBr_3 halogen carrier

Why do halogens not react with benzene without a catalyst?

Delocalised electrons can't polarise Br2Br_2

What type of reagent is used in Friedel-Crafts alkylation?

Haloalkane

What type of compound is produced in Friedel-Crafts acylation?

Aromatic ketone

What happens when bromine water is added to benzene at room temperature without a catalyst?

No reaction; stays orange-brown

Why does benzene undergo substitution rather than addition reactions?

Substitution preserves aromatic stability

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