Carbonyls and Carboxylic Acids (OCR A-Level Chemistry A): Flashcards

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Identifying Aldehydes and Ketones
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Functional group in aldehydes and ketones

Carbonyl group (C=O)

Reagent that detects any carbonyl group

2,4-dinitrophenylhydrazine (2,4-DNP)

Reagent that specifically identifies aldehydes

Tollens' reagent

Colour of Brady's reagent solution

Pale orange

Positive result for 2,4-DNP test

Yellow or orange precipitate

Type of reaction between 2,4-DNP and carbonyls

Condensation reaction (water eliminated)

Positive Tollens' test result for aldehydes

Silver mirror forms

Result when ketones react with Tollens' reagent

No reaction occurs

Product when aldehydes oxidised in Tollens' test

Carboxylic acids

How to identify specific carbonyl using 2,4-DNP derivative

Measure melting point and compare to data table

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