Proton NMR Spectroscopy (OCR A-Level Chemistry A): Quizzes

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Proton NMR Spectroscopy
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How many pieces of information does a proton NMR spectrum reveal about a molecule?

Four

What is the chemical shift value of the TMS reference standard in proton NMR?

δ=0\delta = 0 ppm

At what chemical shift range do carboxylic acid (COOH\text{COOH}) protons typically appear?

δ=10\delta = 10-1212 ppm

What is the most reliable method for identifying equivalent protons in a molecule?

Look for planes of symmetry

How many peaks appear in the proton NMR spectrum of butanedioic acid (HOOCCH2CH2COOH\text{HOOCCH}_2\text{CH}_2\text{COOH})?

Two

If integration values are 4.0 and 6.0, what is the simplified ratio of protons?

2:3

According to the n+1n+1 rule, how many peaks appear for a proton with 2 adjacent protons?

3 (triplet)

What splitting pattern indicates a CH3\text{CH}_3 group on an adjacent carbon?

Quartet

Why are OH\text{OH} and NH\text{NH} proton peaks typically broad in NMR spectra?

They undergo hydrogen bonding

What happens to OH\text{OH} and NH\text{NH} peaks after adding D2O\text{D}_2\text{O} to an NMR sample?

They disappear

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