Optical Isomerism (AQA A-Level Chemistry): Flashcards

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Optical Isomerism
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Isomerism

Same molecular formula, different structures

Optical isomers

Non-superimposable mirror images

Chiral carbon

Carbon bonded to four different groups

Polarimeter

Measures direction & degree of light rotation

Dextrorotatory

Rotates light clockwise, (+)-isomer

Laevorotatory

Rotates light anticlockwise, (-)-isomer

Plane polarised light

Light where all waves vibrate in same plane

Properties of enantiomers

Chemically & physically identical (except light effect)

Thalidomide enantiomers

One sedative, other caused birth defects

Enantiomers & light rotation

Rotate in opposite directions

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