Properties of Alcohols (OCR A-Level Chemistry A): Flashcards

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Properties of Alcohols
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Functional group defining alcohols

−OH-\text{OH} (hydroxyl group)

Molecular formula of methanol

CH3OH\text{CH}_3\text{OH}

Boiling point: alcohols vs alkanes (same C)

Alcohols have higher boiling points

Main intermolecular force in alcohols

Hydrogen bonds

Why alcohols less volatile than alkanes

Hydrogen bonds must be broken for vaporisation

Solubility of methanol & ethanol in water

Completely soluble

Primary alcohol: H atoms on C bearing OH

2 (or 3 for methanol)

Secondary alcohol: H atoms on C bearing OH

1

Tertiary alcohol: H atoms on C bearing OH

0

Effect of longer chain on alcohol properties

More like alkanes, less influence from −OH-\text{OH}

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