Amines (OCR A-Level Chemistry A): Flashcards

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Amines
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Amines based on what structure?

NH3\text{NH}_3 with H replaced by C chains/rings

Amine classification by N groups

Primary (1), secondary (2), tertiary (3)

General structure: primary amine

RNH2\text{RNH}_2

Why amines act as bases

Lone pair on N accepts H+\text{H}^+

Bond type when amine accepts proton

Dative covalent bond

Product: amine + acid

Salt (ammonium salt)

Aliphatic amine prep method

Nucleophilic substitution: haloalkane + NH3\text{NH}_3

Solvent for aliphatic amine prep

Ethanol (prevents alcohol formation)

Why excess ammonia in amine prep

Reduces further substitution to 2°/3° amines

Aromatic amine prep from nitrobenzene

Reduction: Sn/conc HCl (reflux), then NaOH

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