Electrophilic Addition in Alkenes (OCR A-Level Chemistry A): Quizzes

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Electrophilic Addition in Alkenes
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What is an electrophile?

A species that accepts an electron pair

Why are π-electrons in C=C bonds more reactive than σ-bond electrons?

They are less tightly held

What is heterolytic fission?

Both electrons move to one atom

How many bonds does a carbocation have at the positively charged carbon?

Three bonds

How does non-polar Br2\text{Br}_2 become an electrophile when approaching an alkene?

π-electrons induce a dipole in Br—Br

In Markownikoff's rule, where does the hydrogen attach in an unsymmetrical alkene?

Carbon with more H atoms already attached

What is the correct order of carbocation stability?

Tertiary > Secondary > Primary

Why are tertiary carbocations more stable than primary carbocations?

More alkyl groups donate electrons

What is the major product when propene reacts with HBr?

2-bromopropane

What species attacks the carbocation intermediate in electrophilic addition?

A negatively charged nucleophile

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