Electrophilic Addition in Alkenes (OCR A-Level Chemistry A): Flashcards
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Electrophilic addition
Electrophilic addition
Mechanism where alkenes form saturated compounds via addition
Electrophile
Electrophile
Electron-deficient species that accepts an electron pair
Source of high electron density in alkenes
Source of high electron density in alkenes
double bond with -electrons
Heterolytic fission
Heterolytic fission
Bond breaking where both electrons move to one atom
Carbocation
Carbocation
Species with positively charged carbon atom (3 bonds only)
Induced dipole in
Induced dipole in
Temporary dipole from -electrons repelling Br-Br electrons
Markownikoff's rule
Markownikoff's rule
H attaches to C with more H atoms in unsymmetrical addition
Carbocation stability order
Carbocation stability order
Tertiary > Secondary > Primary
Why tertiary carbocations most stable
Why tertiary carbocations most stable
Three alkyl groups donate electrons, dispersing positive charge
Why -electrons make alkenes reactive
Why -electrons make alkenes reactive
Less tightly held than -bond electrons, more accessible
