Electrophilic Addition in Alkenes (OCR A-Level Chemistry A): Flashcards

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Electrophilic Addition in Alkenes
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Electrophilic addition

Mechanism where alkenes form saturated compounds via addition

Electrophile

Electron-deficient species that accepts an electron pair

Source of high electron density in alkenes

C=C\text{C=C} double bond with π\pi-electrons

Heterolytic fission

Bond breaking where both electrons move to one atom

Carbocation

Species with positively charged carbon atom (3 bonds only)

Induced dipole in Br2\text{Br}_2

Temporary dipole from π\pi-electrons repelling Br-Br electrons

Markownikoff's rule

H attaches to C with more H atoms in unsymmetrical addition

Carbocation stability order

Tertiary > Secondary > Primary

Why tertiary carbocations most stable

Three alkyl groups donate electrons, dispersing positive charge

Why π\pi-electrons make alkenes reactive

Less tightly held than σ\sigma-bond electrons, more accessible

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