Disubstitution and Directing Groups (OCR A-Level Chemistry A): Quizzes

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Disubstitution and Directing Groups
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What effect does an activating group have on benzene's reactivity toward electrophiles?

Increases reactivity

How many bromine atoms substitute when phenylamine reacts with bromine?

Three bromine atoms

What conditions are needed for bromination of nitrobenzene?

Catalyst and heating required

Which positions on benzene are defined as ortho relative to a substituent at position 1?

Positions 2 and 6

Which group is a 2- and 4-directing (ortho-para directing) group?

\ce−OH\ce{-OH} hydroxyl group

Which group is a 3-directing (meta-directing) group?

\ce−CN\ce{-CN} cyano group

What is unique about halogens as substituent groups on benzene?

Deactivating but ortho-para directing

Where does the \ceNO2\ce{NO2} group substitute when benzoic acid undergoes nitration?

Position 3 (meta position)

To make 1,4-dichloronitrobenzene from benzene, which substituent should be added first?

Chlorine

What temperature is used for the first nitration of toluene to form 2-nitrotoluene in TNT synthesis?

50°C

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