Infrared Spectroscopy (VCE SSCE Chemistry): Flashcards

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Infrared Spectroscopy
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What does IR spectroscopy identify in organic molecules?

Functional groups

Effect of stronger bonds on IR frequency absorbed

Absorb higher frequency IR radiation

Effect of lighter atoms on IR frequency absorbed

Absorb higher frequency IR radiation

Units for wavenumber in IR spectroscopy

cm1\text{cm}^{-1}

Wavenumber range of fingerprint region

Below 1400 cm11400 \text{ cm}^{-1}

O-H alcohol IR absorption range (cm1\text{cm}^{-1})

32003600 cm13200-3600 \text{ cm}^{-1}, broad

C=O bond IR absorption wavenumber

Around 1700 cm11700 \text{ cm}^{-1}, strong and narrow

O-H carboxylic acid IR absorption range

25003300 cm12500-3300 \text{ cm}^{-1}, very broad

Material for IR sample containers (not glass/plastic)

NaCl or KBr (transparent to IR)

Requirement for molecule to absorb IR radiation

Vibrations must change the overall dipole moment

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