Mass Spectrometry (VCE SSCE Chemistry): Flashcards

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Mass Spectrometry
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MS separation basis

Mass-to-charge ratio (m/zm/z)

MS detection sensitivity range

Parts per billion to parts per trillion

Three stages of MS process

Ionisation, separation, detection

Ionisation in MS creates what

Positively charged ions

Molecular ion peak location

Highest m/zm/z value in spectrum

Base peak characteristics

Tallest peak, 100% relative intensity

Fragment ions definition

Smaller pieces of molecule with lower m/zm/z

Why MS needs vacuum

Prevent air molecule interference

m/zm/z when charge is 1+

Equals molecular mass

Chlorine isotope pattern in spectrum

Two peaks separated by 2 mass units, ~3:1 ratio

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