Organohalogen Compounds in the Environment (OCR A-Level Chemistry A): Flashcards

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Organohalogen Compounds in the Environment
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Organohalogen compounds

Molecules with halogen atoms bonded to carbon chains

Ozone layer altitude and location

Stratosphere, 10-40 km above Earth's surface

Primary function of ozone layer

Absorbs harmful UV-B radiation from the Sun

Why CFCs are chemically stable

Strong carbon-halogen bonds make them unreactive

CFC bond broken first by UV radiation

\ceC−Cl\ce{C-Cl} bond (lowest bond enthalpy)

\ceCl•\ce{Cl•} + \ceO3\ce{O3} reaction product

\ceClO•\ce{ClO•} + \ceO2\ce{O2}

Why \ceCl•\ce{Cl•} acts as catalyst

Regenerated in step 2, attacks more \ceO3\ce{O3} molecules

\ceO3\ce{O3} molecules destroyed per CFC molecule

Approximately 100,000

Montreal Protocol year and purpose

1987, phased out CFCs to protect ozone layer

Why CFC alternatives are safer for ozone

Don't contain chlorine atoms

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